chemisorption: meaning, definition, pronunciation and examples

C2+
UK/ˌkɛmɪˈsɔːpʃən/US/ˌkɛmɪˈsɔːrpʃən/

Technical / Scientific

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Quick answer

What does “chemisorption” mean?

The binding of a gas or dissolved substance to a solid surface via chemical bonding.

Audio

Pronunciation

Definition

Meaning and Definition

The binding of a gas or dissolved substance to a solid surface via chemical bonding.

A type of adsorption involving strong chemical interactions between the adsorbate and the surface, distinct from weaker physical adsorption (physisorption). The process is typically characterized by high heat of adsorption and irreversibility.

Dialectal Variation

British vs American Usage

Differences

No significant difference in meaning or usage. Both use the same spelling 'chemisorption', unlike some '-ise'/-'ize' variations.

Connotations

None beyond the technical meaning.

Frequency

Equally rare and confined to technical domains in both varieties.

Grammar

How to Use “chemisorption” in a Sentence

The chemisorption of [GAS] on [MATERIAL][MATERIAL] exhibits chemisorption of [GAS]Chemisorption occurs at [CONDITION]

Vocabulary

Collocations

strong
strong chemisorptionirreversible chemisorptiondissociative chemisorptionchemisorption processchemisorption of oxygen
medium
undergo chemisorptioncharacterized by chemisorptioninvolve chemisorptionstudy chemisorption
weak
surfacecatalysttemperatureisotherm

Examples

Examples of “chemisorption” in a Sentence

verb

British English

  • The hydrogen molecules are believed to chemisorb onto the platinum surface.
  • The study examines how nitrogen chemisorbs at different temperatures.

American English

  • Oxygen will chemisorb on the fresh aluminum surface, forming a layer.
  • Researchers modeled how CO chemisorbs on the catalyst.

adverb

British English

  • The gas bonded chemisorptively to the substrate.
  • Not used frequently.

American English

  • The species is bound chemisorptively, not reversibly.
  • Not used frequently.

adjective

British English

  • The chemisorptive properties of the new alloy were remarkable.
  • They measured the chemisorptive capacity of the material.

American English

  • A chemisorptive bond is much stronger than a physisorptive one.
  • The process is chemisorptive in nature.

Usage

Meaning in Context

Business

Not used.

Academic

Used in research papers, theses, and advanced textbooks in chemistry, chemical engineering, and materials science.

Everyday

Never used.

Technical

Core term in catalysis, surface science, sensor technology, and gas purification processes.

Vocabulary

Synonyms of “chemisorption”

Neutral

chemical adsorption

Weak

adsorptionsurface bondingadhesion

Vocabulary

Antonyms of “chemisorption”

physisorptionphysical adsorptiondesorption

Watch out

Common Mistakes When Using “chemisorption”

  • Using 'chemisorption' to describe any type of adsorption.
  • Pronouncing it /ˈkɛmɪˌsɔːpʃən/ (with primary stress on the first syllable). Correct is /ˌkɛmɪˈsɔːpʃən/.

FAQ

Frequently Asked Questions

No, chemisorption typically involves strong chemical bonds and is not easily reversed by simply reducing pressure; it often requires significant energy input (e.g., high temperature).

Chemisorption is always exothermic, meaning it releases heat, often a substantial amount.

It is crucial in heterogeneous catalysis, surface science, corrosion studies, semiconductor fabrication, and the design of chemical sensors and gas storage materials.

Yes, it requires a surface with specific active sites capable of forming chemical bonds. Not all surfaces will induce chemisorption for a given gas.

The binding of a gas or dissolved substance to a solid surface via chemical bonding.

Chemisorption is usually technical / scientific in register.

Chemisorption: in British English it is pronounced /ˌkɛmɪˈsɔːpʃən/, and in American English it is pronounced /ˌkɛmɪˈsɔːrpʃən/. Tap the audio buttons above to hear it.

Learning

Memory Aids

Mnemonic

Think of CHEMical + adSORPTION = CHEMISORPTION. It's a chemical handshake, not just a physical touch, between a molecule and a surface.

Conceptual Metaphor

A molecule forming a permanent alliance with a surface (vs. a temporary visit in physisorption).

Practice

Quiz

Fill in the gap
The strong, irreversible binding of carbon monoxide to the palladium surface is a classic example of .
Multiple Choice

What primarily distinguishes chemisorption from physisorption?