coordination compound: meaning, definition, pronunciation and examples

C2
UK/kəʊˌɔːdɪˈneɪʃən ˈkɒmpaʊnd/US/koʊˌɔrdɪˈneɪʃən ˈkɑmpaʊnd/

Technical / Academic

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Quick answer

What does “coordination compound” mean?

A chemical compound where a central metal atom or ion is bonded to surrounding molecules or anions (ligands).

Audio

Pronunciation

Definition

Meaning and Definition

A chemical compound where a central metal atom or ion is bonded to surrounding molecules or anions (ligands).

In chemistry, it describes a molecular structure formed by coordinate covalent bonds, where the ligands donate electron pairs to the central metal. It is a foundational concept in inorganic chemistry and organometallic chemistry, crucial for understanding catalysis, colour theory (in complexes), and biochemical processes (e.g., haemoglobin).

Dialectal Variation

British vs American Usage

Differences

No significant difference in meaning or usage. Spelling of related terms may vary (e.g., 'colour/color theory').

Connotations

Identical. Purely technical with no regional connotative differences.

Frequency

Equally common in UK and US academic and research contexts.

Grammar

How to Use “coordination compound” in a Sentence

[metal] coordinates with [ligands][ligands] coordinate to the [metal]formation of a coordination compound between [metal] and [ligands]The coordination compound consists of [central atom] and [surrounding groups].

Vocabulary

Collocations

strong
synthesis of a coordination compoundstructure of a coordination compoundligands in a coordination compoundmetal centre in a coordination compoundgeometry of a coordination compound
medium
forming a coordination compoundstudy coordination compoundsproperties of coordination compoundsstable coordination compound
weak
new coordination compoundinorganic coordination compoundbiological coordination compound

Examples

Examples of “coordination compound” in a Sentence

verb

British English

  • The copper ion will coordinate with four ammonia molecules.
  • The ligand is designed to coordinate to the metal centre.

American English

  • The copper ion will coordinate with four ammonia molecules.
  • The ligand is designed to coordinate to the metal center.

adverb

British English

  • The ligand is coordinated strongly to the iron atom.
  • The molecules are arranged coordinationally around the centre.

American English

  • The ligand is coordinated strongly to the iron atom.
  • The molecules are arranged coordinationally around the center.

adjective

British English

  • The coordination chemistry of platinum is well-studied.
  • They analysed the compound's coordination geometry.

American English

  • The coordination chemistry of platinum is well-studied.
  • They analyzed the compound's coordination geometry.

Usage

Meaning in Context

Business

Extremely rare. Might appear in highly specific contexts like patents for catalysts or pharmaceutical development reports.

Academic

Core term in university-level chemistry, materials science, and biochemistry textbooks, research papers, and lectures.

Everyday

Virtually never used. The concept is far too specialised for general conversation.

Technical

Ubiquitous in chemistry labs, chemical engineering, research literature on catalysis, spectroscopy, and medicinal inorganic chemistry.

Vocabulary

Synonyms of “coordination compound”

Strong

coordination complex

Neutral

metal complexcomplex compound

Weak

metal-ligand complexcoordination entity

Vocabulary

Antonyms of “coordination compound”

simple salt (e.g., NaCl)covalent molecular compound (e.g., CH4)

Watch out

Common Mistakes When Using “coordination compound”

  • Pronouncing 'coordination' with stress on the first syllable (should be on the third: -dɪ-ˈneɪ-).
  • Using it to refer to general organisational or managerial 'coordination'.
  • Confusing it with a simple mixture or an ionic compound without a defined central atom.

FAQ

Frequently Asked Questions

An ionic compound like NaCl involves simple electrostatic attraction between discrete Na+ and Cl- ions. A coordination compound has a central metal atom/ion that is directly bonded (via coordinate covalent bonds) to specific surrounding molecules or anions (ligands), forming a distinct molecular or complex ion entity.

No, colour depends on the specific metal and ligands, which affect the energy gap for d-electron transitions. Some coordination compounds (like those with Zn2+ or Sc3+ with no d-electrons involved in transitions) are colourless.

Yes, but only outside scientific contexts. In everyday language, 'coordination' refers to organising activities. In chemistry, it refers specifically to the formation of coordinate covalent bonds to a central atom. The context makes the meaning clear.

Haemoglobin is a classic example. The iron(II) ion in its heme group is a central metal coordinated to a porphyrin ring ligand and a histidine residue from the protein, with the sixth site binding oxygen.

A chemical compound where a central metal atom or ion is bonded to surrounding molecules or anions (ligands).

Coordination compound is usually technical / academic in register.

Coordination compound: in British English it is pronounced /kəʊˌɔːdɪˈneɪʃən ˈkɒmpaʊnd/, and in American English it is pronounced /koʊˌɔrdɪˈneɪʃən ˈkɑmpaʊnd/. Tap the audio buttons above to hear it.

Learning

Memory Aids

Mnemonic

Think of a king (central metal ion) in a throne room, surrounded by loyal attendants (ligands) who each offer him a pair of gifts (electron pairs). The entire arrangement is the coordinated royal court – the coordination compound.

Conceptual Metaphor

A HUB AND SPOKES system, where the central metal is the hub and the coordinate bonds are the spokes connecting it to the ligand wheels.

Practice

Quiz

Fill in the gap
A typically features a central metal atom bonded to several surrounding ions or molecules.
Multiple Choice

What is the primary bonding feature of a coordination compound?