graham's law: meaning, definition, pronunciation and examples

Low
UK/ˈɡreɪ.əmz lɔː/US/ˈɡreɪ.əmz lɔː/ or /ˈɡræmz lɔː/

Technical/Scientific

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Quick answer

What does “graham's law” mean?

A law of physics stating that the rate of effusion (or diffusion) of a gas is inversely proportional to the square root of its molar mass.

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Pronunciation

Definition

Meaning and Definition

A law of physics stating that the rate of effusion (or diffusion) of a gas is inversely proportional to the square root of its molar mass.

The principle, discovered by Scottish chemist Thomas Graham, describing the relationship between the mass of gas molecules and their speed. In broader scientific context, it illustrates kinetic theory concepts and is used to compare the behaviour of different gases under similar conditions.

Dialectal Variation

British vs American Usage

Differences

No significant lexical or grammatical differences. Spelling of 'law' and scientific terminology are identical. Potential minor pronunciation differences in the name 'Graham' (/ˈɡreɪ.əm/ vs /ˈɡræm/ or /ˈɡreɪ.əm/).

Connotations

Identical technical meaning and connotation in both varieties.

Frequency

Equally low frequency in both academic scientific registers.

Grammar

How to Use “graham's law” in a Sentence

Graham's law states that...According to Graham's law, ...One can apply Graham's law to...

Vocabulary

Collocations

strong
demonstrate Graham's lawaccording to Graham's lawGraham's law of effusionapply Graham's law
medium
predict using Graham's lawrate described by Graham's lawexperiment on Graham's law
weak
teach Graham's lawproblem involving Graham's lawcalculation based on Graham's law

Examples

Examples of “graham's law” in a Sentence

verb

British English

  • The data were graham's lawed to determine the unknown gas's molar mass.
  • You can graham's law the effusion rates if you know the molar masses.

American English

  • We graham's lawed the experimental results to identify the gas.
  • The process of graham's lawing is straightforward with the correct formula.

adverb

British English

  • The gases behaved graham's law-ly, as predicted.
  • The mixture separated graham's law-wise through the porous barrier.

American English

  • The diffusion proceeded graham's law-fully, matching our model.
  • The rates changed graham's law-ally with the square root of mass.

adjective

British English

  • The graham's law calculation confirmed our hypothesis.
  • We observed a clear graham's law relationship in the data.

American English

  • The graham's law analysis was pivotal to the experiment's conclusion.
  • This is a classic graham's law problem from the textbook.

Usage

Meaning in Context

Business

Virtually never used.

Academic

Exclusively used in chemistry and physics textbooks, lectures, and research papers discussing gas kinetics.

Everyday

Not used in everyday conversation.

Technical

Core term in chemical engineering, physical chemistry, and gas dynamics for calculations involving gas mixing, separation, or leakage rates.

Vocabulary

Synonyms of “graham's law”

Strong

Graham's law of diffusion and effusion

Neutral

Graham's law of effusion

Weak

the inverse square root mass relationship

Watch out

Common Mistakes When Using “graham's law”

  • Misspelling as 'Gram's law' or 'Graham Law' (missing apostrophe and 's').
  • Using it to describe liquid diffusion, which it does not govern.
  • Confusing effusion (through a tiny hole) with general diffusion.

FAQ

Frequently Asked Questions

It was formulated by the Scottish chemist Thomas Graham in the 19th century.

No, it is a law specific to the behaviour of gases.

Effusion is the escape of gas molecules through a tiny hole into a vacuum. Diffusion is the gradual mixing of gases. Graham's law originally described effusion but is often applied to diffusion under similar conditions.

Yes, it is the name of a specific scientific law and is always capitalised.

A law of physics stating that the rate of effusion (or diffusion) of a gas is inversely proportional to the square root of its molar mass.

Graham's law is usually technical/scientific in register.

Graham's law: in British English it is pronounced /ˈɡreɪ.əmz lɔː/, and in American English it is pronounced /ˈɡreɪ.əmz lɔː/ or /ˈɡræmz lɔː/. Tap the audio buttons above to hear it.

Learning

Memory Aids

Mnemonic

Heavy gases move slowly; light gases zip fast. Think: Graham's law is about MASS and SPEED.

Conceptual Metaphor

GAS MOLECULES ARE RACERS: Lighter racers (gases) have a higher speed than heavier ones under the same conditions.

Practice

Quiz

Fill in the gap
According to , a lighter gas will effuse more rapidly than a heavier gas under the same conditions.
Multiple Choice

Graham's law is primarily concerned with which property of gases?

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